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Cation and anion: differences and characteristics (with examples)

May 30, 2025
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A cation is an ion that has a positive charge and an anion is an ion with a negative charge. Both cations and anions are types of ions. An ion is an atom or group of atoms that have an electric charge, i.e., they have a difference between the number of protons and the number of electrons that make up the ion.

Difference Cations Anions
Definition Positively charged ion Negatively charged ion
Formation Formed by loss of electrons Formed by electron gain
Charge Positive charge Negative charge
Types of ions
  • Mono-atomic cations
  • Poly-atomic cations
  • Mono-valent cations
  • Divalent cations
  • Trivalent cations
  • Mono-atomic anions
  • Poly-atomic anions
  • Mono-valent anions
  • Divalent anions
  • Trivalent anions
Examples
  • Sodium ion: Na+
  • Potassium ion: K+
  • Calcium ion: Ca2+
  • Silver ion: Ag+
  • ammonium ion: NH4+
  • Chloride ion: Cl–
  • Oxygen ion: O2-
  • Sulfide ion: S2-
  • Sulfate ion: SO42-
  • Hydroxyl ion: OH–

What is an anion

An anion in chemistry is defined as an ion that is negatively charged because it has excess electrons. An anion is formed when it gains electrons, i.e., it gains one or more negative charges.

Examples of common anions

We present you a list of the different types of anions.

Monoatomic monovalent anions: ions of a single atom with a negative charge.

  • Chloride anion Cl–

  • Fluoride anion F–

  • Bromide anion Br–

  • Iodide I anion–

  • Hydride anion H–

Divalent monoatomic anions: ions of a single atom with two negative charges.

  • Sulfide anion S2-

  • Oxide anion O2-

Trivalent monoatomic anions: ions of a single atom with three negative charges.

  • Nitride anion N3-

  • Phosphide anion P3-

  • Arsenide anion As3-

Polyatomic anions: ions of two or more atoms.

What is a cation

A cation in chemistry is defined as an ion that is positively charged because it lost electrons from its outermost shell. Cations are formed when they lose one or more electrons from their valence shell.

Examples of common cations

We present you a list of different types of cations.

Monoatomic monovalent cations: ions of a single atom with a positive charge.

  • Lithium cation Li+

  • Sodium cation Na+

  • Potassium cation K+

  • Silver cation Ag+

  • Copper (I) cation Cu+

Divalent monoatomic cations: ions of a single atom with two positive charges.

Trivalent monoatomic cations: ions of a single atom with three positive charges.

Polyatomic cations: ions of two or more positively charged atoms.

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Ana Zita Fernandes

PhD in Biochemistry from the Instituto Venezolano de Investigaciones Científicas (IVIC), with a degree in Bioanalysis from the Universidad Central de Venezuela.

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